The ‘ZData’ matrix from the symbolic code appear to be transposed with respect to ‘psi_vals_fs’. This is likely due to the assumptions that fcontour makes with the data. See Algorithms to understand what it is doing. (It may be interpreting ‘y’ as ‘x’ since the arguments are not specifically stated.) Providing the function with appropriate argumentts seems to solve it.
clear
clc
% use the symbolic method to create the stream function for freestream flow
% and plot it
syms xs ys
Uval = 1;
Vval = 0;
psi_fs(xs,ys) = Uval*ys - Vval*xs;
figure(4)
hf = fcontour(psi_fs,[-3 3 -3 3],'k'); %'k' makes all the lines black <— LIMITS CHANGED TO MATCH THE NUMERIC CODE

get(hf)
Annotation: [1x1 matlab.graphics.eventdata.Annotation]
BeingDeleted: off
BusyAction: 'queue'
ButtonDownFcn: ''
Children: [0x0 GraphicsPlaceholder]
ContextMenu: [0x0 GraphicsPlaceholder]
ContourMatrix: [2x432 double]
CreateFcn: ''
DataTipTemplate: [1x1 matlab.graphics.datatip.DataTipTemplate]
DeleteFcn: ''
DisplayName: '{ys}'
Fill: off
Function: [1x1 symfun]
HandleVisibility: 'on'
HitTest: on
Interruptible: on
LevelList: [-3 -2 -1 0 1 2 3]
LevelListMode: 'auto'
LevelStep: 1
LevelStepMode: 'auto'
LineColor: [0 0 0]
LineStyle: '-'
LineWidth: 0.5000
MeshDensity: 71
Parent: [1x1 Axes]
PickableParts: 'visible'
Selected: off
SelectionHighlight: on
Tag: ''
Type: 'functioncontour'
UserData: []
Visible: on
XData: [71x71 double]
XRange: [-3 3]
XRangeMode: 'manual'
YData: [71x71 double]
YRange: [-3 3]
YRangeMode: 'manual'
ZData: [71x71 double]
Zm = hf.ZData
Zm = 71×71
-3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000
-2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143 -2.9143
-2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286 -2.8286
-2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429 -2.7429
-2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571 -2.6571
-2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714 -2.5714
-2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857 -2.4857
-2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000
-2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143 -2.3143
-2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286 -2.2286
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% use the numerical method to create the stream function for freestream
% flow and plot it
xlocs = [-3:.1:3]; % you can use linspace for this
ylocs = [-3:.1:3];
% make the grid of points x horizontal, y vertical
[xmat,ymat] = meshgrid(xlocs,ylocs);
psi_vals_fs = Uval*ymat - Vval*xmat
psi_vals_fs = 61×61
-3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000 -3.0000
-2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000 -2.9000
-2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000 -2.8000
-2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000 -2.7000
-2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000 -2.6000
-2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000 -2.5000
-2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000 -2.4000
-2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000 -2.3000
-2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000 -2.2000
-2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000 -2.1000
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figure(5)
contour(xmat, ymat, psi_vals_fs,'k') % 'k' makes all the lines black

.