U =
Hi Yogeshwari, the error occurs because you're trying to assign a vector (1x2) to a single element of the symbolic array U and V.
U(1) = 0.05 * (1 - tanh(B * (20 * (x - 0.5))));
V(1)=b0*(A-tanh(B*(20*(x-0.5))));
%% results in a 1x2 vector on the right side, which cannot be assigned to a single element on the left
Also double-check your implementation as 'B' is initially defined as a symbolic variable and is later changed to a symbolic vector making the initial declaration redundant.
B=(1/2)*b0*((4*a3*b3-1)/2*a3-1);
B=zeros(1,2,'sym');